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We report the observation and analysis of a new electronic transition in gas-phase vanadium hydride (VH), identified as the C′5Δ–X5Δ (1,0) band with an origin at 14,015 cm− 1 (714 nm). The spectrum was recorded by laser excitation spectroscopy, with laser-induced fluorescence detected to the X5Δ (v =1) level. Dispersed fluorescence measurements enabled a detailed characterization of the vibrationally excited ground state, yielding a vibrational interval of ΔG1/2 = 1606.6(2) cm− 1 . Despite the presence of significant local perturbations—particularly in the Ω =0 and 1 spin components of the C′5Δ state—a full rotational analysis of the spectrum using a Hund’s case (a) Hamiltonian was achieved. Spectroscopic constants including rotational, spin–orbit, spin–rotation, and Λ-doubling parameters are reported for both the new C′5Δ state and the X5Δ (v = 1) level. Additionally, we observed a small local perturbation in the X5Δ₁ (v =1) level near J =9, attributed to homogeneous spin–orbit and heterogeneous L-uncoupling interactions with the previously analyzed A5Π (v =0) state. An X5Δ ~ A5Π coupled Hamiltonian was used to model this perturbation and yielded interaction parameters roughly consistent with semi-empirical estimates. This work represents only the second analyzed spectroscopic transition of gas-phase VH.